This can be done as follows. First, we apply that Arg[z]==Pi/4
is equivaletnt to Re[z]==Im[z]&&Re[z]>=0
. Second, we obtain a polynomial equation instead of a trig equation. Hence,
{{s -> ConditionalExpression[ (1 - \[Lambda])/2 - Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/ 2, kf > 0 && Inequality[0, Less, \[Omega], Less, 2*Pi] && Inequality[2, Less, \[Lambda], Less, Root[-1 + 8*#1^2 - 8*#1^3 + 2*#1^4 & , 4, 0]]], t -> ConditionalExpression[ -1/2*1/(-1 + \[Lambda]) + Sqrt[(1 + 4*((1 - \[Lambda])/2 - Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2) - 4*\[Lambda]*((1 - \[Lambda])/2 - Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2) - 4*((1 - \[Lambda])/2 - Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2)^ 2 + 8*\[Lambda]*((1 - \[Lambda])/2 - Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2)^ 2 - 4*\[Lambda]^2*((1 - \[Lambda])/2 - Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2)^ 2)/(-1 + \[Lambda])^2]/2, kf > 0 && Inequality[0, Less, \[Omega], Less, 2*Pi] && Inequality[2, Less, \[Lambda], Less, Root[-1 + 8*#1^2 - 8*#1^3 + 2*#1^4 & , 4, 0]]]}, {s -> ConditionalExpression[ (1 - \[Lambda])/2 - Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/ 2, kf > 0 && Inequality[0, Less, \[Omega], Less, 2*Pi] && Inequality[ Root[-1 + 8*#1^2 - 8*#1^3 + 2*#1^4 & , 4, 0], Less, \[Lambda], Less, 1 + Sqrt[2]]], t -> ConditionalExpression[ -1/2*1/(-1 + \[Lambda]) - Sqrt[(1 + 4*((1 - \[Lambda])/2 - Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2) - 4*\[Lambda]*((1 - \[Lambda])/2 - Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2) - 4*((1 - \[Lambda])/2 - Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2)^ 2 + 8*\[Lambda]*((1 - \[Lambda])/2 - Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2)^ 2 - 4*\[Lambda]^2*((1 - \[Lambda])/2 - Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2)^ 2)/(-1 + \[Lambda])^2]/2, kf > 0 && Inequality[0, Less, \[Omega], Less, 2*Pi] && Inequality[ Root[-1 + 8*#1^2 - 8*#1^3 + 2*#1^4 & , 4, 0], Less, \[Lambda], Less, 1 + Sqrt[2]]]}, {s -> ConditionalExpression[ (1 - \[Lambda])/2 + Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/ 2, kf > 0 && Inequality[0, Less, \[Omega], Less, 2*Pi] && Inequality[1, Less, \[Lambda], Less, Root[-1 + 8*#1^2 - 8*#1^3 + 2*#1^4 & , 3, 0]]], t -> ConditionalExpression[ -1/2*1/(-1 + \[Lambda]) + Sqrt[(1 + 4*((1 - \[Lambda])/2 + Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2) - 4*\[Lambda]*((1 - \[Lambda])/2 + Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2) - 4*((1 - \[Lambda])/2 + Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2)^ 2 + 8*\[Lambda]*((1 - \[Lambda])/2 + Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2)^ 2 - 4*\[Lambda]^2*((1 - \[Lambda])/2 + Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2)^ 2)/(-1 + \[Lambda])^2]/2, kf > 0 && Inequality[0, Less, \[Omega], Less, 2*Pi] && Inequality[1, Less, \[Lambda], Less, Root[-1 + 8*#1^2 - 8*#1^3 + 2*#1^4 & , 3, 0]]]}, {s -> ConditionalExpression[ (1 - \[Lambda])/2 + Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/ 2, (Inequality[0, Less, \[Lambda], Less, 1] && Inequality[0, Less, \[Omega], Less, 2*Pi] && kf > 0) || (Inequality[2, Less, \[Lambda], Less, Root[-1 + 8*#1^2 - 8*#1^3 + 2*#1^4 & , 4, 0]] && Inequality[0, Less, \[Omega], Less, 2*Pi] && kf > 0) || (Inequality[Root[-1 + 8*#1^2 - 8*#1^3 + 2*#1^4 & , 3, 0], Less, \[Lambda], Less, 2] && Inequality[0, Less, \[Omega], Less, 2*Pi] && kf > 0) || (Inequality[Root[-1 + 8*#1^2 - 8*#1^3 + 2*#1^4 & , 4, 0], Less, \[Lambda], Less, 1 + Sqrt[2]] && Inequality[0, Less, \[Omega], Less, 2*Pi] && kf > 0)], t -> ConditionalExpression[ -1/2*1/(-1 + \[Lambda]) - Sqrt[(1 + 4*((1 - \[Lambda])/2 + Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2) - 4*\[Lambda]*((1 - \[Lambda])/2 + Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2) - 4*((1 - \[Lambda])/2 + Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2)^ 2 + 8*\[Lambda]*((1 - \[Lambda])/2 + Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2)^ 2 - 4*\[Lambda]^2*((1 - \[Lambda])/2 + Sqrt[1 + 2*\[Lambda] - \[Lambda]^2]/2)^ 2)/(-1 + \[Lambda])^2]/2, (Inequality[0, Less, \[Lambda], Less, 1] && Inequality[0, Less, \[Omega], Less, 2*Pi] && kf > 0) || (Inequality[2, Less, \[Lambda], Less, Root[-1 + 8*#1^2 - 8*#1^3 + 2*#1^4 & , 4, 0]] && Inequality[0, Less, \[Omega], Less, 2*Pi] && kf > 0) || (Inequality[Root[-1 + 8*#1^2 - 8*#1^3 + 2*#1^4 & , 3, 0], Less, \[Lambda], Less, 2] && Inequality[0, Less, \[Omega], Less, 2*Pi] && kf > 0) || (Inequality[Root[-1 + 8*#1^2 - 8*#1^3 + 2*#1^4 & , 4, 0], Less, \[Lambda], Less, 1 + Sqrt[2]] && Inequality[0, Less, \[Omega], Less, 2*Pi] && kf > 0)]}}
I leave the rest on your own.