Undocumented Cell options
Please add any more undocumented Cell options that you know to this answer.
WholeCellGroupOpener
John Fultz posted an answer which had an undocumented option
CellPrint[{
Cell["Click to open the section", "Section",
System`WholeCellGroupOpener -> True],
TextCell["Some text"]}]
This produces a section cell that if you click anywhere on it will open and close the whole section.