I'm not really clear on the scope of the question, but this might provide a start.
In[340]:=
PolynomialReduce[1 - Cos[α], t[1] - π (1 - Cos[α]),
Cos[α]][[2]]
Out[340]= t[1]/π
--- edit ---
Here is your example. I change equations to expressions in effect by taking differences. I create a Groebner basis for the defining expressions; that might not be necessary in this example. I order variables so that the one to be eliminated, Cos[alpha-sub-max], is highest. Your Eliminate came close but I think you'd really need to use Cos[alpha...] instead of just the alpha.
In[348]:=
vars = Join[{Cos[Subscript[α, max]]},
Table[Subscript[t, i], {i, 1, 5}]];
polys = Table[
Subscript[t, i] == Pi/i (1 - Cos[Subscript[α, max]]^i), {i,
1, 5}];
gb = GroebnerBasis[polys, vars];
Now we can use PolynomialReduce to rewrite the expression of interest, replacing wherever possible that cosine with variables lower in the term order.
In[351]:=
PolynomialReduce[
1/3*Pi*(Subscript[v, y]^2*Cos[Subscript[α, max]]^3 -
2*Subscript[v, z]^2*Cos[Subscript[α, max]]^3 -
3*Subscript[v, y]^2*Cos[Subscript[α, max]] +
2*Subscript[v, z]^2 + 2*Subscript[v, y]^2), gb, vars][[2]]
Out[351]= Subscript[t, 1]*Subscript[v, y]^2 -
Subscript[t, 3]*Subscript[v, y]^2 +
2*Subscript[t, 3]*Subscript[v, z]^2
--- end edit ---
--- edit 2 ---
I saw (but no longer can locate) a comment asking about situations where there are related variables such as Sin[Subscript[α, max]/2]. This poses two wrinkles. First is that one will need to work with the smallest fractional angle in order to have polynomial relations between all such angles that can be algebraically related. The second is that one must also add the obvious trig relations such as Sin[XXX]^2+Cos[XXX]^2-1 where XXX is this smallest fractional angle. (Actually I am not sure if this relation must be added, or if GroebnerBasis preprocessing will figure that out for you. Assume it must be added by hand and you won't go too far astray.)
--- end edit 2 ---
--- edit 3 ---
Elaborating on edit 2 using an example from a comment, we use more trig variables and relationship polynomials.
In[74]:= vars =
Join[{Sin[Subscript[α, max]/2],
Cos[Subscript[α, max]/2], Sin[Subscript[α, max]],
Cos[Subscript[α, max]]}, Table[Subscript[t, i], {i, 1, 5}]];
polys = Join[{Cos[Subscript[α, max]]^2 +
Sin[Subscript[α, max]]^2 - 1,
Cos[Subscript[α, max]/2]^2 +
Sin[Subscript[α, max]/2]^2 - 1,
Cos[Subscript[α,
max]] - (Cos[Subscript[α, max]/2]^2 -
Sin[Subscript[α, max]/2]^2),
Sin[Subscript[α, max]] -
2*Cos[Subscript[α, max]/2]*
Sin[Subscript[α, max]/2]},
Table[Subscript[t, i] -
Pi/i (1 - Cos[Subscript[α, max]]^i), {i, 1, 5}]];
gb = GroebnerBasis[polys, vars];
In[66]:= p1 =
4/3*k^2*Sin[Subscript[α, max]/2]^4*(3*Pi - t[1])*
Subscript[v, y];
In[80]:= PolynomialReduce[p1, gb, vars][[2]]
Out[80]= -((2*(-3*k^2*Pi*Subscript[t, 1]*Subscript[v, y] +
3*k^2*Pi*Subscript[t, 2]*
Subscript[v, y] +
k^2*Subscript[t, 1]*Subscript[v, y]*t[1] -
k^2*Subscript[t, 2]*Subscript[v, y]*t[1]))/(3*Pi))
Here is another requested example. In this case preprocessing with TrigExpand causes a multiple angle trig term to disappear, allowing the polynomial replacement to work to its fullest capability.
In[91]:= p2 =
1/6*k^2 Pi*(8 - 9*Cos[Subscript[α, max]] +
Cos[3*Subscript[α, max]])*Subscript[v, y];
In[92]:= PolynomialReduce[p2 // TrigExpand, gb, vars][[2]]
Out[92]= 2*(k^2*Subscript[t, 1]*Subscript[v, y] -
k^2*Subscript[t, 3]*Subscript[v, y])
--- end edit 3 ---
ToExpression["$T_j = \\frac\\pi{j} (1- \\cos^j(\\alpha_\t\ ext{max}))$", TeXForm]
(but why should I have to guess?) $\endgroup$