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$\begingroup$=== is for structural equality, == is for mathematical equality. Use the latter. Next time please post copyable code instead of (or in addition to) the image.$\endgroup$
$\begingroup$The point of this answer, @Nicolo, is that if you need both eigenvalues and eigenvectors, you should just use Eigensystem[] at the outset instead of computing them separately.$\endgroup$
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{e, v} = Eigensystem[J]
to make sure they are matched. $\endgroup$===
is for structural equality,==
is for mathematical equality. Use the latter. Next time please post copyable code instead of (or in addition to) the image. $\endgroup$Simplify[J . v[[1]]] === Simplify[e[[1]]*v[[1]]]
orApplySides[Simplify, J . v[[1]] == e[[1]]*v[[1]]]
. $\endgroup$