Mathematica uses the list for almost everything. You can think of a list
as a row for now for purposes of making matrices.
So when you write {{1,2,3,4},{5,6,7,2}}
then this is a matrix of two rows.
To convert this to matrix of 2 columns, you transpose it. So by transposing at the end, you are telling Mathematica, these rows are really columns.
Transpose[{{1, 2, 3, 4}, {5, 6, 7, 2}}]

So always start with the idea that lists are rows. To do what you want for your data:
x = {1.13, 2.56, 3.42, 4.75, 5.39, 6.84, 7.25}
y = {3.83, 4.15, 3.79, 1.78, 0.23, -0.76, -1.25}
mat = {x, y}

The above is matrix with 2 rows. But you want these to be columns, not rows. Then do an extra step
mat = Transpose[mat]

You'll see this alot in Mathematica when working with matrices. You construct the matrix as rows, since that is the natural way for Mathematica, then add a transpose at the end. This is a little different from Matlab.
x = {1.13, ..., 7.25}
) andTranspose
x
andy
afterwards. $\endgroup$