I evaluated this.
{lon1, lat1} = {-76.4408, 38.0825};
{lon2, lat2} = {-76.5054, 38.1413};
{lon3, lat3} = {-76.3546, 38.2446};
{lon4, lat4} = {-76.2900, 38.18582};
dir12 = GeoDirection[{lat1, lon1}, {lat2, lon2}];
dir23 = GeoDirection[{lat2, lon2}, {lat3, lon3}];
dir34 = GeoDirection[{lat3, lon3}, {lat4, lon4}];
dir41 = GeoDirection[{lat4, lon4}, {lat1, lon1}];
{dir12 - dir41,
dir41 - dir34 + Quantity[360, "AngularDegrees"],
dir23 - dir12,
dir34 - dir23
}
So each corner is approximately 90 degrees. However, below it looks like the corners at the top and bottom are about 98 degrees and the corners on the left and right look to be about 82 degrees.
GeoGraphics[{
Polygon[{{lon1,lat1},{lon2,lat2},{lon3,lat3},{lon4,lat4}}]},
GeoRange->{{38.073,38.255},{-76.515,-76.28}}
]
I have macOS v10.15.7 (Catalina) and...
$Version
12.0.0 for Mac OS X x86 (64-bit) (April 7, 2019)
How can I make the rectangle in this GeoGraphics look like a rectangle?