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How can I learn Mathematica that the ham matrix with symbolic elements is Hermitian?

Block[{jz \[Element] Reals, j \[Element] Reals, b \[Element] Reals}, 
      HermitianMatrixQ[{{(jz + 2 b)/2, 0, 0, 0}, {0, (-jz + 2 b)/2, j, 
        0}, {0, j, (-jz - 2 b)/2, 0}, {0, 0, 0, (jz - 2 b)/2}}]]
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    $\begingroup$ Block, With, Module etc. must take assignments, not predicates or assumptions. $\endgroup$ – flinty Jun 30 at 14:19
  • $\begingroup$ Block is used to declare (and assign values to) local variables. You should tell domain restrictions to HermitianMatrixQ. $\endgroup$ – SneezeFor16Min Jun 30 at 15:45
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By using the SameTest option and Simplify:

HermitianMatrixQ[{
  {(jz + 2 b)/2, 0, 0, 0},
  {0, (-jz + 2 b)/2, j, 0},
  {0, j, (-jz - 2 b)/2, 0},
  {0, 0, 0, (jz - 2 b)/2}
  }, SameTest -> (Simplify[#1 - #2, {jz ∈ Reals, j ∈ Reals, b ∈ Reals}] == 0 &)]

(* result: True *)

This option is covered in the documentation

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