First, regarding the substance of the calculation apart from Mathematica's unit handling: I think your input suggests some confusion about what you're trying to calculate. You say
your working days total to 251/7 weeks for a particular year.
I assume that there are 251 working days in that year (this is a fairly typical number). However, your 251/7 number is not compatible with the meaning of 40 hours per week, which refers to a week containing 5 working days. The number of weeks in the year should be 251/5, not 251/7. So, the result you are looking for is 40 * 251/5 = 2008 hours worked in the year. Or, more simply, 8 hours worked on each of 251 working days gives 2008 hours worked. The other answers here guide you to a result of 10040/7 ~ 1434 hours worked, which I suspect is factually wrong for what you are trying to calculate.
After this correction is made in your input, the result from Mathematica is 251/1095 ~ 0.229. This dimensionless result is correct and has a straightforward physical interpretation: It is the worker's duty cycle, the fraction of time they are working. Based on its physical meaning, this number must be between 0 and 1, which is a sanity check on the calculation.
As Carl Woll's answer suggests, the result you wanted to see is the duty cycle expressed in units of hours per year. You are free to convert it to those units, but it is still a dimensionless quantity.
IndependentUnit
form so as to avoid automatic conversions. $\endgroup$