Clear["Global`*"];
k = 5;
j = 2;
s = 1/3;
myDirichletL[k, j, s] :=
Sum[DirichletCharacter[k, j, n]/n^s, {n, 1, Infinity},
Regularization -> "Dirichlet"]
myDirichletL[k, j, s] // N[#, 50] & (* 0.71731601110102824598178333983627154481266327165006 +
0.21553663997474373554157862752378818741609682472521 I *)
DirichletL[k, j, s] // N[#, 50] & (* 0.71731601110102824598178333983627154481266327165006 +
0.21553663997474373554157862752378818741609682472521 I *)
So, for your task,
Clear["Global`*"];
k = 5;
j = 2;
Sum[Conjugate[DirichletCharacter[k, j, n]]/n^s, {n, 1, Infinity},
Regularization -> "Dirichlet"]
$$
5^{-s} \left(\zeta \left(s,\frac{1}{5}\right)-i \zeta \left(s,\frac{2}{5}\right)+i \zeta \left(s,\frac{3}{5}\right)-\zeta \left(s,\frac{4}{5}\right)\right)
$$
Where $\zeta(\cdot, \cdot)$ is HurwitzZeta
Reference
https://mathematica.stackexchange.com/a/287529/79318