I was curious as to if the original workup was right because I was having problems doing this in my head/pencil/paper. Don't judge me.
Anyway, you can't just use MMA's built in commands to simplify things that involve fractions etc because the denominator may be 0 and MMA gives up, At least that's how I always thought of it.
Here's a work around.
As Alexei already pointed out
(4 Sin[a])/(Cos[a]^2 + Sin[a]^2 + r^4 Cos[a]^2 Cos[b]^2 Sin[a]^4 Sin[b]^2) /. {Cos[a]^2 + Sin[a]^2 -> 1}
gives
(4 Sin[a])/(1 + r^4 Cos[a]^2 Cos[b]^2 Sin[a]^4 Sin[b]^2)
In[20]:= expr = (4 Sin[a])/(Cos[a]^2+Sin[a]^2+r^4 Cos[a]^2 Cos[b]^2 Sin[a]^4 Sin[b]^2)/.{Cos[a]^2+Sin[a]^2-> 1}
Out[20]= (4 Sin[a])/(1+r^4 Cos[a]^2 Cos[b]^2 Sin[a]^4 Sin[b]^2)
In[21]:= expr/. {Sin[a]^4-> Sin[a]^4 (1+Cos[2b])/2*1/Cos[b]^2}
Out[21]= (4 Sin[a])/(1+1/2 r^4 Cos[a]^2 (1+Cos[2 b]) Sin[a]^4 Sin[b]^2)
In[22]:= %/.{Sin[b]^2-> Sin[b]^2 (1-Cos[2b])/(2 Sin[b]^2)}//Simplify
Out[22]= (16 Sin[a])/(4+r^4 Cos[a]^2 Sin[a]^4 Sin[2 b]^2)
Now Why MMA refuses to simplify the following I have no idea.
In[24]:= (16 Sin[a])/(4+r^4 Cos[a]^2 Sin[a]^4 Sin[2 b]^2) ((1/4)/(1/4))
Out[24]= (16 Sin[a])/(4+r^4 Cos[a]^2 Sin[a]^4 Sin[2 b]^2)
Doing it manually like this also fails.
In[25]:= ((1/4)16 Sin[a])/((1/4)(4+r^4 Cos[a]^2 Sin[a]^4 Sin[2 b]^2))
Out[25]= (16 Sin[a])/(4+r^4 Cos[a]^2 Sin[a]^4 Sin[2 b]^2)
But if you were to do this manually,
In[26]:= ((1/4)16 Sin[a])/((1/4)4+(1/4)r^4 Cos[a]^2 Sin[a]^4 Sin[2 b]^2)
Out[26]= (4 Sin[a])/(1+1/4 r^4 Cos[a]^2 Sin[a]^4 Sin[2 b]^2)
Give you the answer you seek.
I really need to refresh up on trig. I can't see why
Sin[b]^2 Cos[b]^2 == 1/4 Sin[2b]^2
Someone work that out by hand so I can see it.
To see how I came up with the replacement rules, see below.
In[19]:= Sin[a]^4== Sin[a]^4 (1+Cos[2b])/2*1/Cos[b]^2//Simplify
Out[19]= True
In[17]:= Sin[b]^2== Sin[b]^2 (1-Cos[2b])/(2 Sin[b]^2)//Simplify
Out[17]= True