You can find calligraphic script under the Palettes' Special Characters menu. E.g.
Plot[Sin[x], {x, 0, 6 Pi}, AxesLabel -> {\[ScriptCapitalT], None}]
Otherwise downloadOr, if you specifically want the LaTeX Mathcal font, - apparently cmbsy10 - you can download and install it, and specify it in the Style
option:-
Plot[Sin[x], {x, 0, 6 Pi}, AxesLabel -> {Style["T", FontFamily -> "cmbsy10"], None}]