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lst = {1 -> a, 2 -> {3 -> c, 4 -> d, 5 -> {6 -> f, 7 -> {8 -> h}}}} lst //. Rule[a :Rule[Except[_z, Except[_z]a_], b_] :> Rule[z @ a, b]
{z[1] -> a, z[2] -> {z[3] -> c, z[4] -> d, z[5] -> {z[6] -> f, z[7] -> {z[8] -> h}}}}
lst = {1 -> a, 2 -> {3 -> c, 4 -> d, 5 -> {6 -> f, 7 -> {8 -> h}}}} lst //. Rule[a : Except[_z], b_] :> Rule[z @ a, b]
lst = {1 -> a, 2 -> {3 -> c, 4 -> d, 5 -> {6 -> f, 7 -> {8 -> h}}}} lst //. Rule[Except[_z, a_], b_] :> Rule[z @ a, b]
Also
Replace[lst, Rule[a_, b_] :> Rule[z @ a, b], All]
same result
