As the @george2079 's suggetionsuggetion,I post my solution from a friend as an answer,but I'm sure there are more better method can do this.I accept myself answer just for reader.If anyone have post better solution,I'll change the acceptance.
$Version
"10.3.1 for Microsoft Windows (64-bit) (December 21, 2015)"
string = First@Import["file address"];
Rule @@@ Transpose@{Keys[string],
URLDecode[StringReplace[Values[string], "=" -> "%"],
CharacterEncoding -> "UTF-8"]}
{NameLast->测试,FormattedName->测试,Phone->12345 678 9}