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Using undocumented FrontEnd`ExportPacket command you can get exactly the same formatting as with Copy As ► Plain Text (i.e. without the line breaks and extra spaces): s = First[FrontEndExecute[FrontEnd`ExportPacket[Cell[BoxData[ToBoxes[a]]], "PlainText"]]] {-11 \[Psi]^2 \[Lambda][1]+6 \[Psi] \[Lambda][2],35 \[Psi]^2 \[Lambda][2],11 \[Psi]^2 \[Lambda][1]...



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