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Example: raw = Flatten[Import @ "C:\\Users\\-e\\Documents\\data.xlsx", 1] data = Prepend[raw,{"First", "Second", "Third", "Forth"}] Grid[data, Frame -> All] Output: EDIT In order to have both row and column headers you could do something like this, see example below... Example: (*row and column headers*) columnHeader = {"First", "Second", ...



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