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Performance in parameter estimation from ParametricNDSolve using varied initial conditions

I have 250 data points from a timecourse exeriment in a list, with columns specifying (1) time, (2-4) initial conditions, (5) absorbance reading. I want to fit 4 parameters (k1, k2, k3, k4) in a DAE ...
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Improving NDSolve speed for heavily stiff problems

Having looked around the intergoogles and Mathematica.SE, I thought I'd pose a question with a minimum working example. Here is the situation I am trying to improve: I am solving a 4th order non ...