You can do it nicely by defining a function complex
Clear[complex];
complex[x_] := PL /. sol /. r -> x;
Plot[{complex[r], Hold[Evaluate@D[complex[r], r]]} // Release, {r,0.1, 2}]

Otherwise as mentioned in the comment your definition of complex can also be used!
Clear[complex];
complex = PL /. sol;
Plot[{complex, Hold[Evaluate@D[complex, r]]} // Release, {r, 0.1, 2}]
In the mean time don't forget to notice the Hold issue with the Plot command. To perform symbolic operations (e.g Differentiation) inside Plot you need to use Hold as Plot replaces the function variable with numeric arguments and thus can result into wrong result for the inner symbolic operation.
Read the FAQs! 3) When you see good Q&A, vote them up byclicking the gray triangles, because the credibility of the system is based on the reputation gained by users sharing their knowledge. ALSO, remember to accept the answer, if any, that solves your problem,by clicking the checkmark sign` – chris Nov 6 '12 at 20:38