As the documentation says : LinearSolve[m,b] finds an x which solves the matrix equation m.x == b, i.e. in your case it finds x such that A.x == B (Dot[A,x] == B). However your task is to find A solving an adequate system of 9 linear equations for 6 variables a,b,c,d,e,f knowing that B is an IdentityMatrix. You are trying to solve an overdetermined system of linear equations and there could exist any solutions only if certain compatibility conditions were satisfied.
For your task use simply Solve :
Solve[A == B, {a, b, c, d, e, f}]
{}
or
Reduce[A == B, {a, b, c, d, e, f}]
False
This means that there are no solutions, i.e. the above equation is contradictory.
You could use Variables[A] instead of specifying variables {a, b, c, d, e, f}.
Consider a different matrix equation where we have 4 unknowns and 4 independent equations e.g. :
A1 = {{a + b, a - 2 b}, {a - c, c + d}};
Solve[ A1 == IdentityMatrix[2], {a, b, c, d}]
{{a -> 2/3, b -> 1/3, c -> 2/3, d -> 1/3}}
i.e. there is only one solution.
Edit
Inverse[A] could be a solution assuming that you wanted x in the matrix equation A.x == IdentityMatrix[3] when A was given. There exists an inverse matrix to A under this condition :
Det[ A] != 0
i.e.
-4 b^2 c + 4 a b d + 4 b c f - 4 a d f != 0
Neither A exists nor this assumption can be satisfied when A is defined as in your question and B is an identity matrix.
A? – b.gatessucks Sep 8 '12 at 20:38A == Ithen alsoA^-1 == I. Thus he just wants to finda,b,c,d,e,frather thanA^-1. – Artes Sep 9 '12 at 0:44