What I am trying to do is to get the value of $\chi^2$ for given probability (let us say $\alpha$=0.01) and degrees of freedom (for example df=3).
How do I get that?
Inverse...Distribution functions return something quite different from expected.
Thanks in advance.

Quantile[]?InverseCDF[]?InverseSurvivalFunction[]? You've seen them? Could you elaborate on "something quite different from expected." with a concrete example? – 0x4A4D♦ Sep 7 '12 at 14:28InverseChiSquareDistribution[], it's the distribution followed by the reciprocal of a $\chi^2$-distributed variate... – 0x4A4D♦ Sep 7 '12 at 14:40